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Published in 2020 at "Chemical Papers"
DOI: 10.1007/s11696-020-01228-9
Abstract: Two dinuclear complexes of [LCu(Cl)(μ-Cl)CuCl3][LCu(Cl)(μ-Cl)CuL(H2O)]Cl, 1 and [LCu(Br)(μ-Br)]2Br, 2, with a tridentate ligand of 3-((pyridin-2-ylmethyl)amino)propanamide, L, were prepared and characterized by physicochemical (elemental analyses, molar conductance measurements, thermogravimetry) and spectroscopic (IR, UV–vis) data. The crystal…
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Keywords:
chromotropism properties;
structural chromotropism;
tridentate ligand;
tridentate ... See more keywords
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Published in 2018 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2018.06.008
Abstract: Abstract A C2-symmetric, chiral bis-cyclosulfinamide-olefin ligand composed of two 1-oxo-2,3-dihydro-1,2-benzisothiazole moieties with rigid skeletons and a conformationally flexible butenylene chain is disclosed for the first time. HRMS and 1H NMR analyses verify that the in…
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Keywords:
cyclosulfinamide olefin;
symmetric chiral;
chiral bis;
tridentate ligand ... See more keywords
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Published in 2020 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.0c02683
Abstract: Neutral Cu(I) and Ag(I) complexes with a new rigid tridentate N,P,P ligand (dmpzpp, 3,5-dimethyl-1-(2-((2-(di-o-tolyl)phosphanyl) (o-tolyl)-phosphanyl)phenyl)-1H-pyrazole), giving Cu(dmpzpp)Cl 6, C...
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Keywords:
rigid tridentate;
tridentate ligand;
new type;
complexes new ... See more keywords
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Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c12504
Abstract: In biological systems, many biomacromolecules (e.g., heme proteins) are capable of switching their states reversibly in response to external stimuli, endowing these natural architectures with a high level of diversity and functionality. Although tremendous efforts…
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Keywords:
tridentate ligand;
responsive tridentate;
wreath;
metallo supramolecular ... See more keywords