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   Articles with "triel" as a keyword



On the Synthesis, Structure and Reactivity of MesDPM Triel Dihydrides

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recommendations! Published in 2025 at "European Journal of Inorganic Chemistry"

DOI: 10.1002/ejic.202500403

Abstract: Herein, the simple synthesis of triel dihydride complexes with the sterically demanding 1,5,9‐trimesityldipyrromethene (MesDPM) ligand is reported. With these compounds, reactivity studies are carried out, opening access to new classes of MesDPM triels. All compounds… read more here.

Keywords: structure reactivity; synthesis structure; reactivity mesdpm; synthesis ... See more keywords

Triel bonds in RZH2···NH3: hybridization, solvation, and substitution

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recommendations! Published in 2019 at "Journal of Molecular Modeling"

DOI: 10.1007/s00894-019-4089-1

Abstract: The influence of hybridization, substitution, and solvation on the triel bond has been investigated in the complexes of RZH2···NH3 (Z = B and Al). The magnitude of the π-hole on the triel atom is related to the… read more here.

Keywords: triel bond; triel; hole; hybridization ... See more keywords

One-Electron Boron–Carbon Triel Bonding

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recommendations! Published in 2025 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.5c13589

Abstract: Aiming to interrogate the possibility of heteronuclear B–C one-electron σ-bonding, we have prepared a naphthalene-based platform ([5]+) decorated at its peri-positions by a carbenium and a boryl unit separated by a B–C distance of 2.994(4)… read more here.

Keywords: one electron; boron carbon; triel; bond ... See more keywords

The curious case of co-planarity in di-nuclear triel complexes: a density functional investigation.

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recommendations! Published in 2024 at "Dalton transactions"

DOI: 10.1039/d4dt02453b

Abstract: Density functional investigation of intramolecular triel (Tr) bonding present in di-nuclear aryl complexes of group 13 elements having general formula [(Tr)Me2(2,6-(X)2C6H3O)]2 (Tr = B, Al, Ga, In & Tl and X = OMe, OEt, OH,… read more here.

Keywords: functional investigation; triel; complexes group; density functional ... See more keywords