Triel bonds in RZH2···NH3: hybridization, solvation, and substitution
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Molecular Modeling"
DOI: 10.1007/s00894-019-4089-1
Abstract: The influence of hybridization, substitution, and solvation on the triel bond has been investigated in the complexes of RZH2···NH3 (Z = B and Al). The magnitude of the π-hole on the triel atom is related to the… read more here.
Keywords: triel bond; triel; hole; hybridization ... See more keywords
π-Hole Triel Bonds between TrPhX2 (Tr = B, Al, Ga; X = F, Cl, Br, CH3, OH) and (BH)2(NHC)2 (NHC = Nitrogen-Heterocyclic Carbene)
Sign Up to like & getrecommendations! Published in 2023 at "Crystals"
DOI: 10.3390/cryst13060872
Abstract: The π-hole triel bond formed by (BH)2(NHC)2 (NHC denotes nitrogen-heterocyclic carbene) and TrPhX2 (Tr = B, Al, and Ga; X = F, Cl, Br, CH3, and OH) was investigated computationally, with the B=B bond in… read more here.
Keywords: interaction energy; interaction; triel bond;
Triel Bond Formed by Malondialdehyde and Its Influence on the Intramolecular H-Bond and Proton Transfer
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DOI: 10.3390/molecules27186091
Abstract: Malondialdehyde (MDA) engages in a triel bond (TrB) with TrX3 (Tr = B and Al; X = H, F, Cl, and Br) in three modes, in which the hydroxyl O, carbonyl O, and central carbon… read more here.
Keywords: proton transfer; triel bond; trb; bond ... See more keywords