Different reactivity patterns for [M(trien)]2+/3+ (M = NiII and CoIII) toward azido ions: Cationic charge dependence and different mode of ligand enfolding for 1D chain formation
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DOI: 10.1016/j.molstruc.2018.11.078
Abstract: Abstract Linear and flexible N4 ligand trien (N′-{2-(2-aminoethylamino)-ethyl}-ethane-1,2-diamine) has been used to show octahderal coordination around NiII ions and cis coordination from two ancillary bridges from azide ions. Room temperature reaction of trien with Ni(NO3)·6H2O… read more here.
Keywords: coiii; chain; trien no3; coordination ... See more keywords