Preparation and Characterization of the Triflate Complex [Cp*(dppe)FeOSO2 CF3 ]: A Convenient Access to Labile Five- and Six-Coordinate Iron(I) and Iron(II) Complexes
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DOI: 10.1002/ejic.201901086
Abstract: Treatment of the iron hydride [Cp*(dppe)FeH] (1) with methyl triflate (CH3OSO2CF3) yielded the iron triflate adduct [Cp*(dppe)FeOSO2CF3] (4, 85 %). In the solid state, the triflate is coordinated at the iron center as shown by… read more here.
Keywords: triflate; dppe; complex dppe; iron ... See more keywords
Selective conversion of glucose into lactic acid with immobilized ytterbium triflate
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DOI: 10.1007/s11144-018-1448-3
Abstract: Ytterbium triflate was immobilized on SBA-15 via chemical grafting and co-condensation and the catalytic performance of the immobilized ytterbium triflate for the selective conversion of glucose into lactic acid was investigated in this paper. The… read more here.
Keywords: triflate; immobilized ytterbium; ytterbium triflate; lactic acid ... See more keywords
Synthesis and electronic characterization of mixed diimine ligand rhodium(III) complexes using a versatile triflate precursor
Sign Up to like & getrecommendations! Published in 2017 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.02.011
Abstract: Abstract We report here the first general, high purity, high yield synthesis of thirteen mixed diimine ligand complexes of rhodium(III), nine of which are new and four which are known and were made as controls.… read more here.
Keywords: triflate; diimine ligand; electronic characterization; mixed diimine ... See more keywords
Structural Diversity in Divalent Group 14 Triflate Complexes Involving Endocyclic Thia-Macrocyclic Coordination
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DOI: 10.1021/acs.inorgchem.2c03613
Abstract: A highly unusual series of M(II) (M = Ge, Sn, Pb) complexes with endocyclic thioether macrocyclic coordination and with coordination numbers ranging from three to nine have been prepared by the reaction of [9]aneS3 (1,4,7-trithiacyclononane),… read more here.
Keywords: triflate; coordination; group; macrocyclic coordination ... See more keywords
Stereocontrolled radical polymerization of acrylamides by ligand-accelerated catalysis
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DOI: 10.1038/s41428-020-00444-0
Abstract: The role of alcohol in the Yb(OTf)3- and Y(OTf)3-catalyzed stereoselective radical polymerization of acrylamides is clarified. The coordination of an alcohol to the metal triflate generates a new complex, which increases both the polymerization rate… read more here.
Keywords: triflate; polymerization; radical polymerization; polymerization acrylamides ... See more keywords