Heterocyclic nitrogen donor complexes of aluminium, gallium and indium with weakly coordinating triflate anions
Sign Up to like & getrecommendations! Published in 2021 at "Polyhedron"
DOI: 10.1016/j.poly.2021.115367
Abstract: Abstract The reactions of M(OTf)3 (M = Al, Ga, In; OTf = CF3SO3–) with 2,2′:6′,2′’- terpyridyl (terpy) in CH2Cl2 gave mer-[M(OTf)3(terpy)], whilst with 2,2′-bipyridyl (bipy) and 1,10-phenanthroline (phen) the products isolated were cis-[M”(OTf)2(bipy)2]OTf (M” = Al, Ga), cis-[In(OTf)(H2O)(bipy)2][OTf]2, cis-[Al(OTf)2(phen)2][OTf]… read more here.
Keywords: otf; triflate anions; cis otf; bipy otf ... See more keywords
Establishing the Role of Triflate Anions in H2 Activation by a Cationic Triorganotin(IV) Lewis Acid
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DOI: 10.1021/acscatal.0c02023
Abstract: Cationic Lewis acids (LAs) are gaining interest as targets for frustrated Lewis pair (FLP)-mediated catalysis. Unlike neutral boranes, which are the most prevalent LAs for FLP hydrogenations, the Lewis acidity of cations can be tuned… read more here.
Keywords: role triflate; cationic triorganotin; activation cationic; establishing role ... See more keywords