Regioselective Ring Opening of Glycidol to Monoalkyl Glyceryl Ethers Promoted by an [OSSO]-FeIII Triflate Complex.
Sign Up to like & getrecommendations! Published in 2019 at "ChemSusChem"
DOI: 10.1002/cssc.201901329
Abstract: A new Fe(III)-triflate complex, bearing a bis-thioether-di-phenolate [OSSO]-type ligand, is reported to promote the ring-opening of glycidol with alcohols under mild reaction conditions (0.05 mol% of catalyst and 80 °C). The reaction proceeds with high… read more here.
Keywords: ring opening; glyceryl ethers; opening glycidol; triflate complex ... See more keywords
A Stiboranyl Platinum Triflate Complex as an Electrophilic Catalyst
Sign Up to like & getrecommendations! Published in 2020 at "Organometallics"
DOI: 10.1021/acs.organomet.0c00193
Abstract: With the view of developing electrophilic late-transition-metal catalysts, we have now synthesized [(o-(Ph2P)C6H4)2Sb(OTf)2]Pt(OTf) (2) and [(o-(iPr2P)C6H4)2Sb(OTf)2]Pt(OTf) (4) by treatment of the... read more here.
Keywords: electrophilic catalyst; platinum triflate; otf; complex electrophilic ... See more keywords