Isolation and Reactions of Imidoyl Fluorides Generated from Oxime Using the Diethylaminosulfur Trifluoride/Tetrahydrofuran (DAST-THF) System.
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DOI: 10.1021/acs.orglett.3c01063
Abstract: Fluorination of oximes with the relatively mild diethylaminosulfur trifluoride/tetrahydrofuran (DAST-THF) system affords imidoyl fluorides. These compounds were isolated, and their structures were confirmed by X-ray single-crystal structure analysis. Reaction of imidoyl fluorides with various nucleophiles… read more here.
Keywords: system; diethylaminosulfur trifluoride; trifluoride tetrahydrofuran; dast thf ... See more keywords