Investigation of Iodonium Trifluoroborate Zwitterions as Bifunctional Arene Reagents.
Sign Up to like & getrecommendations! Published in 2017 at "Organic letters"
DOI: 10.1021/acs.orglett.7b03307
Abstract: The synthesis of a new family of iodonium zwitterions, in which the formal anion is a trifluoroborate moiety, is reported. These reagents present very good stability and have high resistance toward benzyne formation. Their structures… read more here.
Keywords: investigation iodonium; trifluoroborate; zwitterions bifunctional; iodonium ... See more keywords
Primary trifluoroborate-iminiums enable facile access to chiral α-aminoboronic acids via Ru-catalyzed asymmetric hydrogenation and simple hydrolysis of the trifluoroborate moiety
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d1sc07065g
Abstract: This work describes the first preparation and application of primary trifluoroborate-iminiums (pTIMs) as a new, easily accessible and valuable class of organoboron derivatives. An array of structurally diverse pTIMs was prepared from potassium acyltrifluoroborates in… read more here.
Keywords: primary trifluoroborate; aminoboronic acids; chiral aminoboronic; access chiral ... See more keywords
One-Step 18F-Labeling and Preclinical Evaluation of Prostate-Specific Membrane Antigen Trifluoroborate Probes for Cancer Imaging
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Nuclear Medicine"
DOI: 10.2967/jnumed.118.216598
Abstract: After the identification of the high-affinity glutamate-ureido scaffold, the design of several potent 18F- and 68Ga-labeled tracers has allowed spectacular progress in imaging recurrent prostate cancer by targeting the prostate-specific membrane antigen (PSMA). We evaluated… read more here.
Keywords: step; trifluoroborate; prostate cancer; cancer imaging ... See more keywords