Selective C-H trifluoromethoxylation of (hetero)arenes as limiting reagent
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DOI: 10.1038/s41467-020-16451-x
Abstract: Methods for direct C-H trifluoromethoxylation of arenes and heteroarenes are rare, despite the importance of trifluoromethoxylated compounds for pharmaceuticals, agrochemicals, and material sciences. Especially selective C-H trifluoromethoxylation of pyridines remains a formidable challenge. Here we… read more here.
Keywords: selective trifluoromethoxylation; trifluoromethoxylation arenes; trifluoromethoxylation; arenes heteroarenes ... See more keywords
Photocatalytic trifluoromethoxylation of arenes and heteroarenes in continuous-flow
Sign Up to like & getrecommendations! Published in 2020 at "Beilstein Journal of Organic Chemistry"
DOI: 10.3762/bjoc.16.111
Abstract: The first example of photocatalytic trifluoromethoxylation of arenes and heteroarenes under continuous-flow conditions is described. Application of continuous-flow microreactor technology allowed to reduce the residence time up to 16 times in comparison to the batch… read more here.
Keywords: heteroarenes continuous; trifluoromethoxylation arenes; photocatalytic trifluoromethoxylation; continuous flow ... See more keywords