Fe-Catalyzed Alkylazidation of α-Trifluoromethylalkenes: An Access to Quaternary Stereocenters Containing CF3 and N3 Groups.
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DOI: 10.1021/acs.orglett.3c00439
Abstract: A concise Fe-catalyzed alkylazidation of α-trifluoromethylalkenes via a C-C bond cleavage/radical addition/azidation cascade is described. This protocol features a broad substrate scope, excellent functional group compatibility, and the ability to be performed on a gram… read more here.
Keywords: quaternary stereocenters; trifluoromethylalkenes access; catalyzed alkylazidation; alkylazidation trifluoromethylalkenes ... See more keywords