Copper-Catalyzed Reductive Trifluoromethylation of Alkyl Iodides with Togni's Reagent.
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DOI: 10.1021/acs.orglett.8b02005
Abstract: This work illustrates a reductive cross-electrophile coupling protocol for trifluoromethylation of alkyl iodides under Cu-catalyzed/Ni-promoted reaction conditions. The use of diboron esters as the terminal reductant allows the effective generation of the alkyl-CF3 products with… read more here.
Keywords: alkyl; alkyl iodides; togni reagent; trifluoromethylation alkyl ... See more keywords