Manganese‐Dioxide‐Catalyzed Trifluoromethylation and Azidation of Styrenyl Olefins via Radical Intermediates
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DOI: 10.1002/ajoc.201700508
Abstract: Manganese dioxide catalyzed trifluoromethylation of styrenes and enolacetates using Langlois reagent is reported. Employing oxygen/air as the oxidant, styrenes afforded a mixture of the trifluoromethylacohol and ketone products in good overall yield. The protocol also… read more here.
Keywords: trifluoromethylation azidation; dioxide catalyzed; catalyzed trifluoromethylation; manganese dioxide ... See more keywords