Zn-Mediated Scalable Synthesis of Trifluoromethylphosphines from Phosphine Chlorides and CF3Br.
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DOI: 10.1021/acs.orglett.3c01253
Abstract: Trifluoromethylphosphines represent a rare kind of phosphine with unique electronic withdrawing properties, which lead to some distinctive reactivities. The reported TFMPhos, products from nucleophilic or electrophilic trifluoromethylation of substrates, requiring one or more steps and… read more here.
Keywords: mediated scalable; phosphine chlorides; trifluoromethylphosphines phosphine; synthesis trifluoromethylphosphines ... See more keywords