Six coordinate capped trigonal bipyramidal complexes
Sign Up to like & getrecommendations! Published in 2017 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2017.06.019
Abstract: Abstract This review collects the examples of a rare, six-coordinate geometry, the capped trigonal bipyramid (CTB). Examples have been identified for d 0 Sc(III), Y(III), Zr(IV), Ta(V), d 4 Mo(II), d 2 Mo(IV) and W(IV),… read more here.
Keywords: coordinate capped; capped trigonal; trigonal bipyramidal; six coordinate ... See more keywords
Coordination properties of aqueous vanadate complexes with nitrogen- and oxygen-containing multidentate ligands
Sign Up to like & getrecommendations! Published in 2017 at "Polyhedron"
DOI: 10.1016/j.poly.2017.05.056
Abstract: Abstract The complexation properties of aqueous vanadate with diethanolamine (DEA) and iminodiacetate (IDA) derivatives were elucidated by NMR spectroscopy and DFT calculations. The coordination geometries of vanadium in 1:1 complexes of the DEA derivatives were… read more here.
Keywords: coordination; trigonal bipyramidal; aqueous vanadate; properties aqueous ... See more keywords
Synthesis and characterization of trigonal bipyramidal FeIII complexes and their solution behavior.
Sign Up to like & getrecommendations! Published in 2021 at "Polyhedron"
DOI: 10.1016/j.poly.2021.115384
Abstract: A series of air-stable trigonal bipyramidal FeIII complexes supported by a redox non-innocent NNN pincer ligand, Cz tBu(PyrR)2 - (R = iPr, Me, or H), were synthesized, fully characterized, and utilized for the investigation of… read more here.
Keywords: feiii; bipyramidal feiii; trigonal bipyramidal; feiii complexes ... See more keywords
Bite-Angle-Regulated Coordination Geometries: Tetrahedral and Trigonal Bipyramidal in Ni(II) with Biphenyl-Appended (2-Pyridyl)alkylamine N,N′-Bidentate Ligands
Sign Up to like & getrecommendations! Published in 2017 at "ACS Omega"
DOI: 10.1021/acsomega.7b00119
Abstract: Two simple biphenyl-appended (2-pyridyl)alkylamine N-bidentate ligands, Le and Lm, having ethylene and methylene spacers between donor groups, with bite angles Le ≈ 100° and Lm ≈ 80°, dictate pseudotetrahedral and trigonal-bipyramidal geometries in six high-spin… read more here.
Keywords: bidentate ligands; appended pyridyl; trigonal bipyramidal; alkylamine bidentate ... See more keywords
Investigation of the magnetic anisotropy in a series of trigonal bipyramidal Mn(ii) complexes.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt02187f
Abstract: Understanding how the magnetic anisotropy in simple coordination complexes can be manipulated is instrumental to the development of single-molecule magnets (SMMs). Clear strategies can then be designed to control both the axial and transverse contributions… read more here.
Keywords: trigonal bipyramidal; investigation; anisotropy series; magnetic anisotropy ... See more keywords
d+id chiral superconductivity in a triangular lattice from trigonal bipyramidal complexes
Sign Up to like & getrecommendations! Published in 2018 at "Physical Review B"
DOI: 10.1103/physrevb.97.165110
Abstract: We model the newly predicted high-$T_c$ superconducting candidates constructed by corner-shared trigonal bipyramidal complexes with an effective three-orbital tight-banding Hamiltonian and investigate the pairing symmetry of their superconducting states driven by electron-electron interactions. Our combined… read more here.
Keywords: chiral superconductivity; superconductivity triangular; trigonal bipyramidal; bipyramidal complexes ... See more keywords