AXHg3P2S8 (A = Rb, Cs; X = Cl, Br): New Excellent Infrared Nonlinear Optical Materials with Mixed‐Anion Chalcohalide Groups of Trigonal Planar [HgS2X]3− and Tetrahedral [HgS3X]5−
Sign Up to like & getrecommendations! Published in 2021 at "Advanced Optical Materials"
DOI: 10.1002/adom.202100563
Abstract: A series of nonlinear optical (NLO) chalcohalides AXHg3P2S8 (A = Rb, Cs; X = Cl, Br), which contain various Hg‐based building units including mixed‐anion trigonal planar [HgS2X]3− and tetrahedral [HgS3X]5−, are successfully synthesized. These compounds… read more here.
Keywords: mixed anion; trigonal planar; anion; nonlinear optical ... See more keywords
Transformation of trigonal planar B4 into zigzag B4 units within the new boride series Ti2–xM1+x–δIr3+δB3 (x = 0.5 for M = V–Mn, x = 0 for M = Mn–Ni and δ < 0.2)
Sign Up to like & getrecommendations! Published in 2020 at "Solid State Sciences"
DOI: 10.1016/j.solidstatesciences.2020.106294
Abstract: Abstract In metal‒rich borides, numerous boron fragments Bn (n = 2, 3, 4, 5, 6) have been discovered, the B4 units being the most versatile with four different shapes (bent, zigzag, trigonal planar and tetrahedral). We report… read more here.
Keywords: boride series; zigzag; trigonal planar; new boride ... See more keywords
Low-Valent, Multiply Bonded, Trigonal-Planar Sb Complex: Rational Syntheses, Dual Acidic/Basic Properties, and Unexpected Semiconducting Characteristics.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c02820
Abstract: A 4-center, 6π-conjugated, multiply bonded trigonal-planar complex, [Sb{Cr(CO)5}3]- (1), was synthesized via the hydride abstraction of [HSb{Cr(CO)5}3]2- (1-H) with HBF4·H2O, with the release of high yields of H2. The oxidation state of the Sb atom… read more here.
Keywords: planar complex; low valent; trigonal planar; multiply bonded ... See more keywords
Investigation into the Effects of a Trigonal-Planar Ligand Field on the Electronic Properties of Lanthanide(II) Tris(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb).
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b00664
Abstract: In recent work we have reported the synthesis and physical properties of near-linear Ln(II) (Ln = lanthanide) complexes utilizing the bulky bis(silylamide) {N(SiiPr3)2}. Herein, we synthesize trigonal-planar Ln(II) complexes by employing a smaller bis(silylamide), {N(SitBuMe2)2}… read more here.
Keywords: trigonal planar; bis silylamide; effects trigonal; silylamide complexes ... See more keywords