Large Energy Barrier and Magnetization Hysteresis at 5 K for a Symmetric {Dy2} Complex with Spherical Tricapped Trigonal Prismatic DyIII Ions.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b00026
Abstract: The introduction of the Schiff base ligand N-salicylidene-2-amino-5-chlorobenzoic acid (sacbH2) in 4f-metal chemistry has afforded a new dinuclear complex, [Dy2(NO3)4(sacbH)2(H2O)2(MeCN)2] (1), with the metal ions adopting a rare spherical tricapped trigonal prismatic coordination geometry. The… read more here.
Keywords: chemistry; hysteresis; tricapped trigonal; trigonal prismatic ... See more keywords
A trigonal prismatic anionic iron(III) complex of a radical o-iminobenzosemiquinonate derivative: structural and spectral analyses
Sign Up to like & getrecommendations! Published in 2017 at "New Journal of Chemistry"
DOI: 10.1039/c7nj01212h
Abstract: A new iron(III) complex, [Et3NH][FeIII(L2−˙)2] (1) with a substituted o-aminophenol based ligand is reported. Complex 1 is an anionic complex with a triethylammonium cation in the lattice. It contains two O,O,N-coordinated o-iminobenzosemiquinonate(2−) radical anions with… read more here.
Keywords: iii; high spin; spin; trigonal prismatic ... See more keywords
Visible-light excited luminescent trigonal prismatic metallocages from a template-directed assembly
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry frontiers"
DOI: 10.1039/d1qi00409c
Abstract: Trigonal prismatic metallocages based on Cu3Pz3 and Cu2I2/Cu2Br2 with 24-component were assembled via a template-directed strategy. They showed rare visible-light responsive red emissions based on Cu2I2/Cu2Br2 coordination chromophores. read more here.
Keywords: prismatic metallocages; light excited; template directed; visible light ... See more keywords
C2H2 capture and separation in a MOF based on Ni6 trigonal-prismatic units.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc01506d
Abstract: A honeycomb MOF, based on rare Ni6 trigonal-prismatic supermolecular building blocks, was fabricated by utilizing an unexploited [1,1'-biphenyl]-3,3',5,5'-tetracarboxylic acid linker with -NH2 substituent groups. The MOF contains novel building blocks and an enchanting structure, and… read more here.
Keywords: ni6 trigonal; mof based; capture separation; trigonal prismatic ... See more keywords
Modelling the structural disorder in trigonal-prismatic coordinated transition metal dichalcogenides
Sign Up to like & getrecommendations! Published in 2023 at "Journal of Applied Crystallography"
DOI: 10.1107/s1600576723001589
Abstract: The structural disorder in trigonal-prismatic coordinated transition metal layered dichalcogenides is investigated. The structural model taking into account stacking faults, correlated displacement of atoms and average crystallite size is assessed by fitting to the X-ray… read more here.
Keywords: transition metal; trigonal prismatic; disorder trigonal; structural disorder ... See more keywords