Trinuclear clusters containing 2-aminopyridinate/pyrimidinate ligands as electrocatalysts for proton reduction
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DOI: 10.1016/j.jorganchem.2017.09.015
Abstract: Abstract Triiron and triruthenium clusters containing capping 2-aminopyridinate/pyrimidinate ligands are developed as functional models of the [FeFe]-hydrogenase for electrocatalytic reduction of protons to hydrogen. The 48-electron clusters Fe 3 (CO) 9 (μ 3 -pyNH)(μ-H) (… read more here.
Keywords: reduction; proton reduction; pyrimidinate ligands; aminopyridinate pyrimidinate ... See more keywords