Anion and Temperature Responsive Molecular Switches Based on Trimetallic Complexes of Ru(II) and Os(II) That Demonstrate Advanced Boolean and Fuzzy Logic Functions.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03644
Abstract: Anion- and temperature-induced alteration of the photoredox behaviors of our recently reported trimetallic complexes was carried out to fabricate potential molecular switches. The triads [(phen)2Ru(d-HIm-t)M(t-HIm-d)Ru(phen)2]6+ (phen = 1,10-phenanthroline, d-HIm-t = heterotopic bipyridine-terpyridne type bridging ligand,… read more here.
Keywords: temperature; trimetallic complexes; molecular switches; anion temperature ... See more keywords
Bi- and trimetallic complexes with macrocyclic xanthene-4,5-diNHC ligands.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d1dt03857e
Abstract: Three different types of bimetallic NHC-metal complexes were synthesized, whose NHC units are attached at the 4,5-positions of xanthene. The NHC units are in close proximity and are designed such that each carbene coordinates one… read more here.
Keywords: xanthene; xanthene dinhc; complexes macrocyclic; trimetallic complexes ... See more keywords
A Versatile Approach to Access Trimetallic Complexes Based on Trisphosphinite Ligands
Sign Up to like & getrecommendations! Published in 2020 at "Molecules"
DOI: 10.3390/molecules25030593
Abstract: A straightforward method for the preparation of trisphosphinite ligands in one step, using only commercially available reagents (1,1,1-tris(4-hydroxyphenyl)ethane and chlorophosphines) is described. We have made use of this approach to prepare a small family of… read more here.
Keywords: trisphosphinite ligands; access trimetallic; versatile approach; approach access ... See more keywords