Synthesis, structural and spectroscopic features of 2,2,2-trichloro-N-[(trimethylsilyl)methyl]acetamide and 2,2,2-trimethyl-N-[(trimethylsilyl)methyl]acetamide
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2019.02.030
Abstract: Abstract 2,2,2-Trichloro-N-[(trimethylsilyl)methyl]acetamide and 2,2,2-trimethyl-N-[(trimethylsilyl)-methyl]acetamide were prepared by reaction of N-[(trimethylsilyl)methyl]amine with acid chlorides of the corresponding acids. The crystal structure of 2,2,2-trichloro-N-[(trimethylsilyl)methyl]acetamide was studied by X-ray analysis. Quantum chemical calculations (DFT 6-311++G**) were performed and… read more here.
Keywords: methyl acetamide; acetamide trimethyl; trichloro trimethylsilyl; trimethylsilyl methyl ... See more keywords
A molecular substitutional disorder case study suitable for instruction: L2CrII(THF)/L2[(trimethylsilyl)methyl]CrIII (L is 2,5-bis{[(2,6-diisopropylphenyl)imino]methyl}pyrrol-1-ide).
Sign Up to like & getrecommendations! Published in 2022 at "Acta crystallographica. Section C, Structural chemistry"
DOI: 10.1107/s2053229622003825
Abstract: A solution of CrII and CrIII complexes, bis(2,5-bis{[(2,6-diisopropylphenyl)imino]methyl}pyrrol-1-ido)(tetrahydrofuran)chromium(II)-bis(2,5-bis{[(2,6-diisopropylphenyl)imino]methyl}pyrrol-1-ido)[(trimethylsilyl)methyl]chromium(III) (0.88/0.12), [Cr(C30H38N3)2(C4H8O)]0.88[Cr(C30H38N3)2(C4H11Si)]0.12 or L2CrII(THF)/L2[(trimethylsilyl)methyl]CrIII (L = 2,5-bis{[(2,6-diisopropylphenyl)imino]methyl}pyrrol-1-ide and THF is tetrahydrofuran), in pentane crystallizes in the monoclinic space group P21/c. The structure obtained shows most of the… read more here.
Keywords: methyl pyrrol; trimethylsilyl methyl; diisopropylphenyl imino; imino methyl ... See more keywords