Syntheses, structures and catecholase activities of homo‐ and hetero‐trinuclear cobalt(II) complexes constructed from an acyclic naphthalenediol‐based bis(Salamo)‐type ligand
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DOI: 10.1002/aoc.3818
Abstract: A series of homo- and hetero-trinuclear cobalt(II) complexes [Co3(L)(OAc)2(CH3CH2OH)(H2O)] (1), [Co2Ba(L)(OAc)2] (2) and [Co2Ca(L)(OAc)2]·CHCl3 (3), containing an acyclic naphthalenediol-based ligand H4L were synthesized. All the three complexes were characterized by elemental analyses, IR, UV–vis spectra… read more here.
Keywords: trinuclear cobalt; cobalt complexes; homo hetero; acyclic naphthalenediol ... See more keywords
Trinuclear Cobalt(II) Triple Helicate with a Multidentate Bithiazolebis(oxamate) Ligand as a Supramolecular Nanomagnet.
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DOI: 10.1021/acs.inorgchem.2c00291
Abstract: The cobalt(II)-mediated self-assembly of the potentially tris(chelating) N,N'-2,2'-(4,4'-bithiazole)bis(oxamate) (dabtzox) ligand gives a new metal-organic supramolecular nanomagnet of formula K6Co3(dabtzox)3·8H2O·MeOH (1) featuring a unique linear triple-stranded trinuclear structure of the helicate type. read more here.
Keywords: cobalt; trinuclear cobalt; oxamate; supramolecular nanomagnet ... See more keywords