Trinuclear Complexes Derived from R/S Schiff Bases – Chiral Single‐Molecule Magnets
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700078
Abstract: Invited for the cover of this issue is the group of Albert Escuer from Universitat de Barcelona, Spain, in collaboration with the group of Lorenzo Di Bari from Universita di Pisa, Italy. The cover image shows… read more here.
Keywords: schiff bases; complexes derived; derived schiff; chiral single ... See more keywords
Synthesis, characterization and antibacterial activity evaluation of trinuclear Ni(II) complexes with N-substituted salicylhydrazide ligands
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DOI: 10.1016/j.poly.2017.01.019
Abstract: Abstract Three novel trinuclear Ni(II) complexes, [Ni3(L1)2(py)4] (1), [Ni3(L2)2(H2O)2(DMA)2] (2) and [Ni3(L3)2(py)4] (3), with trianionic pentadentate ligands derived from salicylhydrazide with N-acyl substituents [H3L1 = N2-crotonoylsalicylhydrazide, H3L2 = N2-(3,3-dimethylacryloyl)salicylhydrazide, H3L3 = N2-cinnamoylsalicylhydrazide] were synthesized and characterized by elemental analysis, spectroscopic techniques,… read more here.
Keywords: antibacterial activity; characterization antibacterial; synthesis characterization; trinuclear complexes ... See more keywords
Bi and trinuclear complexes in palladium carboxylate-assisted C-H activation reactions.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c7dt04269h
Abstract: The role of polynuclear species in C-H activations assisted by palladium carboxylates has not been clear so far. The summary of the key findings covering this issue shows its important role under certain conditions. However,… read more here.
Keywords: carboxylate assisted; complexes palladium; palladium carboxylate; palladium ... See more keywords
Control of structure, stability and catechol oxidase activity of copper(II) complexes by the denticity of tripodal platforms
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DOI: 10.1039/c7nj02013a
Abstract: Copper(II) complexes of a new polydentate tripodal ligand trenpyz (L, tris[2-(5-pyrazolylmethyl)aminoethyl]amine) were characterized in both solution and solid states. A combined evaluation of potentiometric UV-Vis and EPR data provided both thermodynamic and structural information on… read more here.
Keywords: catechol oxidase; copper complexes; denticity tripodal; copper ... See more keywords
Mixed azido/phenoxido bridged trinuclear Cu(ii) complexes of Mannich bases: Synthesis, structures, magnetic properties and catalytic oxidase activities.
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DOI: 10.1039/c8dt01400k
Abstract: Three similar Mannich base ligands viz. N,N-bis(3,5-dimethyl-2-hydroxybenzyl)-N',N'-dimethyl-1,3-diaminopropane (H2L1), N,N-bis(3,5-dimethyl-2-hydroxybenzyl)-N',N'-dimethyl-1,2-diaminoethane (H2L2) and N,N-bis(3,5-dimethyl-2-hydroxybenzyl)-N',N'-diethyl-1,2-diaminoethane (H2L3) upon reaction with Cu(CH3COO)2·H2O produced dinuclear complexes [Cu2L21-3]. The reaction of each of these isolated dimeric species with Cu(ClO4)2·6H2O and NaN3 resulted… read more here.
Keywords: dimethyl; dimethyl hydroxybenzyl; 2cu h2o; bis dimethyl ... See more keywords
Two novel fan-shaped trinuclear Pt(ii) complexes act as G-quadruplex binders and telomerase inhibitors.
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DOI: 10.1039/d0dt01767a
Abstract: Two new trinuclear Pt(ii) complexes {[Pt(dien)]3(tib)}(NO3)6 (1) and {[Pt(dpa)]3(tib)}(NO3)6 (2) (dien: diethylenetriamine, dpa: bis-(2-pyridylmethyl)amine, tib: 1,3,5-tris(1H-imidazol-1-yl)benzene) have been designed, synthesized, characterized and applied to a series of biochemical studies. We found that both of the… read more here.
Keywords: human telomeric; fan shaped; quadruplex; shaped trinuclear ... See more keywords
1D iron(II)-1,2,4-triazolic chains with spin crossover assembled from discrete trinuclear complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00004k
Abstract: We report on a molecular cationic iron(II) complex with a 4-amino-1,2,4-triazole ligand and a tetraiodomercurate anion exhibiting an incomplete spin crossover (SCO). The complex exhibits an unusual disordered structure with a linear arrangement of ligand… read more here.
Keywords: crossover assembled; triazolic chains; iron triazolic; spin crossover ... See more keywords