Triphenylphosphine-Catalyzed Alkylative Iododecarboxylation with Lithium Iodide under Visible Light.
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DOI: 10.1021/acs.orglett.0c03173
Abstract: Under irradiation of 456 nm blue light-emitting diodes, PPh3 catalyzes the iododecarboxylation of aliphatic carboxylic acid derived N-(acyloxy)phthalimide with lithium iodide as an iodine source. The reaction delivers primary, secondary, and bridgehead tertiary alkyl iodides… read more here.
Keywords: triphenylphosphine catalyzed; lithium iodide; catalyzed alkylative; iododecarboxylation ... See more keywords