Synthesis of a rhodium(III) triphenylphosphine complex via C S bond cleavage of an azo-thioether ligand: X-ray structure, electrochemistry and catalysis towards transfer hydrogenation of ketones
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DOI: 10.1016/j.poly.2018.10.061
Abstract: Abstract A new rhodium(III) triphenylphosphine complex having the general formula [Rh(PPh3)2(L)Cl] (1) was synthesized by C S bond cleavage of an ONS donor azo-thioether ligand (L-CH2Ph). The complex was thoroughly characterized by various spectroscopic techniques.… read more here.
Keywords: electrochemistry; triphenylphosphine complex; iii triphenylphosphine; structure ... See more keywords