Structure, UV spectroscopic and electrochemical properties of 2-methyl-8-quinolinolato rhodium (I) complexes, containing carbonyl, triphenylphosphine or triphenylphosphite ligands
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DOI: 10.1016/j.molstruc.2021.131557
Abstract: Abstract The known Rh(2-Me-8-Oxq)(CO)2 complex (1) was prepared through treatment of dicarbonyl(acetylacetonate)rhodium (I) with 2-methyl-8-hydroxyquinoline for the first time. The reactions of 1 with triphenylphosphine and triphenylphosphite result in complexes Rh(2-Me-8-Oxq)(PPh3)(CO) (2) and Rh(2-Me-8-Oxq)[P(OPh)3](CO) (3)… read more here.
Keywords: electrochemical properties; rhodium; methyl quinolinolato; spectroscopic electrochemical ... See more keywords