Articles with "triple decker" as a keyword



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Multi-Decker Emissive Supramolecular Architectures Based on Shape-Complementary Ligands Pair.

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Published in 2022 at "Small"

DOI: 10.1002/smll.202202167

Abstract: Dye aggregates have attracted a great deal of attention due to their widespread applications in organic light-emitting devices, light-harvesting systems, etc. However, the strategies to precisely control chromophores with specific spatial arrangements still remain a… read more here.

Keywords: supramolecular; decker; complementary ligands; triple decker ... See more keywords

More about the redox behavior of late transition metal triple-decker complexes with cyclo-triphosphorus

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Published in 2018 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2017.07.014

Abstract: Abstract The syntheses of the new triple-decker complexes [(triphos)Co(μ,η 3:3 -P 3 )Ru(triphos)](BPh 4 ) 2 ; ( CoP 3 Ru )(BPh 4 ) 2 , [(triphos)Co(μ,η 3:3 -P 3 )Os(triphos)](BPh 4 ) 2 ;… read more here.

Keywords: bph; triple decker; decker complexes; triphos triphos ... See more keywords
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(C4Me4)Co-containing triple-decker complexes with bridging heterocyclic ligands

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Published in 2018 at "Journal of Organometallic Chemistry"

DOI: 10.1016/j.jorganchem.2018.06.025

Abstract: Abstract (C 4 Me 4 )Co-containing triple-decker complexes with bridging boron and phosphorus heterocyclic ligands [(C 4 Me 4 )Co(μ-η:η-L)MCp*] + ( 1 : M = Fe, L = C 5 H 5 BMe; 2 : M = Fe, L = C 4… read more here.

Keywords: containing triple; complexes bridging; decker complexes; triple decker ... See more keywords
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Triple-Decker Iron and Cobalt Complexes Featuring a Bridging 1,2-Diboratabenzene Ligand.

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Published in 2023 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.3c00558

Abstract: Neutral triple-decker iron and cobalt complexes with a bridging 1,2-diboratabenzene ligand were accessed by reactions of a dilithium 1,2-diboratabenzene reagent with [Cp*FeCl]2 and [Cp*CoCl]2, respectively. While 1,2-diboratabenzene metal complexes are known, these represent the first… read more here.

Keywords: bridging diboratabenzene; iron cobalt; decker iron; cobalt complexes ... See more keywords
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Syntheses and Structures of Triple-Decker Complexes Incorporating Octamethylruthenocene and Nonamethylruthenocene

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Published in 2019 at "Organometallics"

DOI: 10.1021/acs.organomet.9b00250

Abstract: Five new diruthenium triple-decker complexes were synthesized by the reaction of ruthenium electrophiles with metallocenes of ruthenium. At 40 °C, the reaction of [(C5R5)Ru(NCMe)3]+ (R = H, Me) wit... read more here.

Keywords: decker complexes; triple decker; syntheses structures; structures triple ... See more keywords
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Zirconium arene triple-decker sandwich complexes: synthesis, electronic structure and bonding.

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Published in 2017 at "Chemical communications"

DOI: 10.1039/c7cc07083g

Abstract: Reduction of a permethylpentalene zirconium(iv) chloride complex [η8-Pn*Zr(μ-Cl)3/2]2(μ-Cl)2Li·THFx with KC8 in benzene results in activation of the aromatic solvent to yield an "inverted sandwich" complex, [η8-Pn*Zr]2(μ-η6:η6-C6H6) (1). The reactions in toluene, cumene, o-xylene and m-xylene… read more here.

Keywords: decker sandwich; triple decker; sandwich complexes; zirconium ... See more keywords
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The Triple-Decker Complex [Cp*Fe(µ,η5:η5-P5)Mo(CO)3] as a Building Block in Coordination Chemistry

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Published in 2019 at "Molecules"

DOI: 10.3390/molecules24020325

Abstract: Although the triple-decker complex [Cp*Fe(µ,η5:η5-P5)Mo(CO)3] (2) was first reported 26 years ago, its reactivity has not yet been explored. Herein, we report a new high-yielding synthesis of 2 and the isolation of its new polymorph… read more here.

Keywords: decker complex; triple decker; chemistry; coordination chemistry ... See more keywords

Redox-Triggered Switching of Conformational State in Triple-Decker Lanthanide Phthalocyaninates

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Published in 2022 at "Molecules"

DOI: 10.3390/molecules27196498

Abstract: Double- and triple-decker lanthanide phthalocyaninates exhibit unique physical-chemical properties, particularly single-molecule magnetism. Among other factors, the magnetic properties of these sandwiches depend on their conformational state, which is determined via the skew angle of the… read more here.

Keywords: conformational state; triple decker; lanthanide phthalocyaninates; decker lanthanide ... See more keywords
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Structure Determination of Binuclear Triple-Decker Phthalocyaninato Complexes by NMR via Paramagnetic Shifts Analysis Using Symmetry Peculiarities

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Published in 2022 at "Molecules"

DOI: 10.3390/molecules27227836

Abstract: The detailed knowledge about the structure of multinuclear paramagnetic lanthanide complexes for the targeted design of these compounds with special magnetic, sensory, optical and electronic properties is a very important task. At the same time,… read more here.

Keywords: structure; structure determination; triple decker; analysis ... See more keywords