Copper(II) complexes of N3O tripodal ligands appended with pyrene and polyamine groups: Anti-proliferative and nuclease activities.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2017.11.006
Abstract: A series of tripodal ligands based on the 2-tert-butyl-4-R-6-phenol was synthesized, where R=aldehyde (HL1), R=putrescine-pyrene (HL2) and R=putrescine (HL3). A dinucleating ligand wherein a putrescine group connects two tripodal moieties was also prepared (H2L4). The… read more here.
Keywords: copper complexes; complexes n3o; nuclease; tripodal ligands ... See more keywords
Enhancement of Terbium(III)-Centered Luminescence by Tuning the Triplet Energy Level of Substituted Pyridylamino-4-R-Phenoxo Tripodal Ligands.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c00023
Abstract: A series of luminescent phenoxo-bridged dinuclear TbIII complexes with tripodal ligands, 2,2'-[[(2-pyridinylmethyl)imino]di(methylene)]-bis(4-R-phenol), where R = CH3 (LCH3) (I), Cl (LCl) (II), CH3O (LCH3O) (III), COOCH3 (LCOOCH3) (IV), were prepared to probe the effect of para-substitution… read more here.
Keywords: iii; energy; triplet; level ... See more keywords
Custom Coordination Environments for Lanthanoids: Tripodal Ligands Achieve Near-Perfect Octahedral Coordination for Two Dysprosium-Based Molecular Nanomagnets.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.6b03118
Abstract: Controlling the coordination sphere of lanthanoid complexes is a challenging critical step toward controlling their relaxation properties. Here we present the synthesis of hexacoordinated dysprosium single-molecule magnets, where tripodal ligands achieve a near-perfect octahedral coordination.… read more here.
Keywords: perfect octahedral; coordination; near perfect; achieve near ... See more keywords
Tailoring the local environment around metal ions: a solution chemical and structural study of some multidentate tripodal ligands.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt00104e
Abstract: Manganese(ii), copper(ii) and zinc(ii) complexes of four polydentate tripodal ligands (tachpyr (N,N',N''-tris(2-pyridylmethyl)-cis,cis-1,3,5-triaminocyclohexane), trenpyr (tris[2-(2-pyridylmethyl)aminoethyl]amine, tach3pyr (N,N',N''-tris(3-pyridylmethyl)-cis,cis-1,3,5-triaminocyclohexane) and tren3pyr (tris[2-(2-pyridylmethyl)aminoethyl]amine)) were characterized in both solution and solid states. A combined evaluation of potentiometric, UV-VIS, NMR and… read more here.
Keywords: copper; metal; tris pyridylmethyl; tripodal ligands ... See more keywords
Ln(III) complexes with triptycene based tripodal ligands: speciation and equilibria
Sign Up to like & getrecommendations! Published in 2018 at "New Journal of Chemistry"
DOI: 10.1039/c8nj00252e
Abstract: Triaminotriptycene was used as a rigid anchoring platform for preparing several organic ligands for Ln(III) complexation. In this work we present detailed speciation studies with a tripodal ligand L6 possessing terminal carboxamide coordinating moieties. The… read more here.
Keywords: triptycene based; based tripodal; iii complexes; tripodal ligands ... See more keywords
Fluorinated click-derived tripodal ligands drive spin crossover in both iron(II) and cobalt(II) complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01005d
Abstract: Control of the spin state of metal complexes is important because it leads to a precise control over the physical properties and the chemical reactivity of the metal complexes. Currently, controlling the spin state in… read more here.
Keywords: spin; tripodal ligands; metal complexes; spin state ... See more keywords