Hyperporous Carbon from Triptycene‐Based Hypercrosslinked Polymer for Iodine Capture
Sign Up to like & getrecommendations! Published in 2019 at "Advanced Materials Interfaces"
DOI: 10.1002/admi.201900249
Abstract: Considering the nuclear fuel reprocessing conditions at 75 °C and the oxidizability of iodine, thermal and chemical stabilities are especially important for porous materials to enrich iodine. However, most organic or metal coordinated porous materials… read more here.
Keywords: capture; hyperporous carbon; carbon; hypercrosslinked polymer ... See more keywords
Triptycene-Based Molecular Rods for Langmuir-Blodgett Monolayers.
Sign Up to like & getrecommendations! Published in 2022 at "ChemPlusChem"
DOI: 10.1002/cplu.202200023
Abstract: Herein we introduce fully modular synthesis leading to three representative examples of rigid molecular rods that are intended to form sturdy monolayers on various surfaces. These molecules contain two triptycene units that are designed to… read more here.
Keywords: rods langmuir; langmuir blodgett; blodgett monolayers; molecular rods ... See more keywords
Triptycene-based porous polymers regulated by diarylethenes
Sign Up to like & getrecommendations! Published in 2018 at "Dyes and Pigments"
DOI: 10.1016/j.dyepig.2018.06.007
Abstract: Abstract Linear and star triptycene-based porous polymers regulated by diarylethenes were constructed via Pd (0)-catalyzed Suzuki coupling reaction, respectively. Both triptycene-based porous polymers performed reversible photochromism in solid state but exhibited distinctive solvent-dependent photochromism in… read more here.
Keywords: triptycene based; porous polymers; based porous; regulated diarylethenes ... See more keywords
Synthesis, characterization and adsorption studies of a novel triptycene based hydroxyl azo- nanoporous polymer for environmental remediation
Sign Up to like & getrecommendations! Published in 2020 at "Journal of environmental chemical engineering"
DOI: 10.1016/j.jece.2019.103558
Abstract: Abstract Gradual increase in CO2 emission due to energy production from fossils fuels is a major contributor to global warming. Alternatively, “carbon free” nuclear energy generates radioactive and carcinogenic iodine vapors. Thus, the need to… read more here.
Keywords: environmental remediation; triptycene based; based hydroxyl; co2 ... See more keywords
Post-crosslinking of triptycene-based Tröger's base polymers with enhanced natural gas separation performance
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Membrane Science"
DOI: 10.1016/j.memsci.2018.04.013
Abstract: Abstract A novel triptycene-based diamine, 2,6-diaminotriptycene-14-carboxylic acid, was synthesized and used for preparing carboxylic acid containing triptycene-based Troger's base copolymers, CoPIM-TB-1 and CoPIM-TB-2, with another diamine monomer, 2,6-diaminotriptycene. The copolymers were subsequently post-crosslinked by glycidol… read more here.
Keywords: separation performance; triptycene based; gas; base ... See more keywords
Circularly Polarized Luminescent Triptycene-Based Polymers
Sign Up to like & getrecommendations! Published in 2018 at "ACS Macro Letters"
DOI: 10.1021/acsmacrolett.8b00106
Abstract: A series of chiral fluorescent polymers containing optically active triptycene units in the main chain were synthesized via Sonogashira–Hagihara coupling copolymerizations of (R,R)- or (S,S)-2,6-diethynyltriptycene with a range of diiodoaryls. Their optical and chiroptical properties… read more here.
Keywords: polarized luminescent; luminescent triptycene; triptycene based; circularly polarized ... See more keywords
Triptycene-Based Luminescent Materials in Homoconjugated Charge-Transfer Systems: Synthesis, Electronic Structures, AIE Activity, and Highly Tunable Emissions
Sign Up to like & getrecommendations! Published in 2020 at "ACS Omega"
DOI: 10.1021/acsomega.0c03565
Abstract: We have developed a new family of luminescent materials featuring through-space charge transfer from electron donors to acceptors that are electronically separated by triptycene. Most of these molecules are highly fluorescent, and modulation of their… read more here.
Keywords: triptycene based; based luminescent; luminescent materials; charge transfer ... See more keywords
Three-Dimensional Triptycene-Based Covalent Organic Frameworks with ceq or acs Topology.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c12499
Abstract: The growth of three-dimensional covalent organic frameworks (3D COFs) with new topologies is still considered as a great challenge due to limited availability of high-connectivity building units. Here we report the design and synthesis of… read more here.
Keywords: three dimensional; triptycene based; ceq acs; topology ... See more keywords
A triptycene-based two-dimensional porous organic polymeric nanosheet
Sign Up to like & getrecommendations! Published in 2017 at "Polymer Chemistry"
DOI: 10.1039/c7py01122a
Abstract: The greater structural versatility of two-dimensional polymeric nanosheets could be available through the development of a bottom-up polymerization strategy compared with top-down nanosheets (such as graphene and metal chalcogenides). However, rational synthesis by solution polymerization… read more here.
Keywords: dimensional porous; based two; triptycene based; two dimensional ... See more keywords
Ln(III) complexes with triptycene based tripodal ligands: speciation and equilibria
Sign Up to like & getrecommendations! Published in 2018 at "New Journal of Chemistry"
DOI: 10.1039/c8nj00252e
Abstract: Triaminotriptycene was used as a rigid anchoring platform for preparing several organic ligands for Ln(III) complexation. In this work we present detailed speciation studies with a tripodal ligand L6 possessing terminal carboxamide coordinating moieties. The… read more here.
Keywords: triptycene based; based tripodal; iii complexes; tripodal ligands ... See more keywords
Triple-stranded triptycene-based metallo-supramolecular helicate displaying efficient encapsulation of bulky guest molecules.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc05974b
Abstract: Triple-stranded metallo-supramolecular helicates were readily constructed by achieving a coordination of the gallium(iii) cation by ligands based on 2,7- and 2,6-disubstituted triptycenes. The significance of these building blocks in the construction of helicates with the… read more here.
Keywords: metallo supramolecular; based metallo; triptycene based; triple stranded ... See more keywords