Visible-Light-Driven Oxidation of Amines to Imines in Air Catalyzed by Polyoxometalate-Tris(bipyridine)ruthenium Hybrid Compounds.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01243
Abstract: The development of visible-light photocatalysts for the selective oxidative coupling of amines to imines is an area of great interest. Herein, four hybrid compounds based on polyoxometalate anions and tris(bipyridine)ruthenium cations, Ru(bpy)3[M6O19] (M = Mo,… read more here.
Keywords: bipyridine ruthenium; amines imines; spectroscopy; hybrid compounds ... See more keywords
Taming Tris(bipyridine)ruthenium(II) and Its Reactions in Water by Capture/Release with Shape-Switchable Symmetry-Matched Cyclophanes
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c13028
Abstract: Electron/proton transfers in water proceeding from ground/excited states are the elementary reactions of chemistry. These reactions of an iconic class of molecules—polypyridineRu(II)—are now controlled by capturing or releasing three of them with hosts that are… read more here.
Keywords: symmetry matched; chemistry; shape switchable; water ... See more keywords
Crystal structure of tris(2,2′-bipyridine)cobalt(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide)
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DOI: 10.1107/s2056989018018261
Abstract: Polynitrile anions are known for their ability to combine with transition metals and co-ligands to form ternary systems. Here we report on the crystal structure of tris(2–2′-bipyridine)cobalt(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide). read more here.
Keywords: bis tetracyano; bipyridine cobalt; tris bipyridine; structure tris ... See more keywords
Multi-Week Cycling of a Nonaqueous Flow Battery Using Tris-Bipyridine Iron (II) Triflate without Additional Supporting Electrolyte
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DOI: 10.1149/1945-7111/acd873
Abstract: Tris-bipyridine iron (II) triflate was synthesized and used as an active species to demonstrate a symmetric disproportionation redox-flow-battery chemistry that works without a supporting electrolyte. Solutions of this coordination complex salt (0.1 M in acetonitrile),… read more here.
Keywords: iron triflate; flow battery; bipyridine iron; supporting electrolyte ... See more keywords