Luminescent Re(I) scorpionates supported by tris(2-pyridyl)phosphine and its derivatives
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.120136
Abstract: Abstract A series of luminescent Re(I) scorpoinates has been synthesized by treatment of Re(CO)5Br with tris(2-pyridyl)phosphine (Py3P) as well as its oxide or sulfide (Py3P=O and Py3P=S). The reaction of Re(CO)5Br with Py3P affords a… read more here.
Keywords: scorpionates supported; tris pyridyl; luminescent scorpionates; py3p ... See more keywords
Site-Isolated Main-Group Tris(2-pyridyl)borate Complexes by Pyridine Substitution and Their Ring-Opening Polymerization Catalysis.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01289
Abstract: Tris(2-pyridyl)borates are an emerging class of scorpionate ligands, distinguished as exceptionally robust and electron-donating. However, the rapid formation of inert homoleptic complexes with divalent metals has so far limited their catalytic utility. We report site-isolating… read more here.
Keywords: borate; chemistry; pyridyl borate; site ... See more keywords
Bis(2-pyridyl) and Tris(2-pyridyl) Compounds of Gallium and Indium via a Redox-Transmetalation Route.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b02872
Abstract: Reactions of the tris(2-pyridyl)lead(II) compound [LiPb(2-py6OtBu)3] (1) with trialkyl compounds of the group 13 elements gallium and indium resulted in the bis(2-pyridyl) and tris(2-pyridyl) gallate complexes [LiGaEt2(2-py6OtBu)2]2 (2), [LiGaR2(2-py6OtBu)2(THF)] (R = iPr (3), tBu (4)),… read more here.
Keywords: pyridyl tris; tris pyridyl; pyridyl; gallium indium ... See more keywords
Tris(2-pyridyl)phosphine as a versatile ligand for pnictogen acceptors.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01526g
Abstract: We report cationic complexes of arsenic and antimony with the tris(2-pyridyl)phosphine ligand. Chloride ion abstraction from AsCl3 using TMSOTf in the presence of the ligand gives [P(Pyr)3As][OTf]3, in which the trication adopts a C3v symmetric… read more here.
Keywords: phosphine versatile; phosphine; tris pyridyl; antimony ... See more keywords
Luminescence behaviour of Au(I)-Cu(I) heterobimetallic coordination polymers based on alkynyl-tris(2-pyridyl)phosphine Au(I) complexes.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt02583f
Abstract: A set of alkynyl-tris(2-pyridyl)phosphine Au(i) complexes was synthesized and characterized. Free coordination functions on the ligand environment periphery, namely 'scorpionate' PPy3 and the C[triple bond, length as m-dash]C bond, allowed these ditopic metalloligands to be… read more here.
Keywords: coordination; heterobimetallic coordination; tris pyridyl; coordination polymers ... See more keywords
FeII/III and MnII complexes based on 2,4,6-tris(2-pyridyl)-triazine: synthesis, structures, magnetic and biological properties
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DOI: 10.1039/d2ra04868j
Abstract: Reaction of the polypyridyl ligand 2,4,6-tris(2-pyridyl)-s-triazine (tpt) with mono- and polynuclear Fe(iii) or Mn(ii) precursors, specifically tri- or hexanuclear Fe(iii) pivalates (piv−), [Mn6O2(piv)10(Hpiv)4] and Mn(ii) isobutyrate (ib−), in various solvents and under various reaction conditions… read more here.
Keywords: triazine; mnii; tpt; piv ... See more keywords
Tris(2-Pyridyl)Arsine as a New Platform for Design of Luminescent Cu(I) and Ag(I) Complexes
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DOI: 10.3390/molecules27186059
Abstract: The coordination behavior of tris(2-pyridyl)arsine (Py3As) has been studied for the first time on the example of the reactions with CuI, CuBr and AgClO4. When treated with CuI in CH2Cl2 medium, Py3As unexpectedly affords the… read more here.
Keywords: dimer cu2; arsine new; cu2 py3as; pyridyl arsine ... See more keywords