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Published in 2019 at "Chirality"
DOI: 10.1002/chir.23064
Abstract: Tripodal metal complexes have been widely used for catalysis and more recently also for molecular recognition applications. Their ability in recognition and signal amplification of chiral substrates is because of the setup of the ligand…
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Keywords:
tris pyridylmethyl;
amine based;
pyridylmethyl amine;
zinc tris ... See more keywords
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Published in 2020 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2020.129773
Abstract: Abstract Osteosarcoma (OS) is a malignant bone tumor and its occurrence is associated with high levels of microRNAs (miRNAs) and critical protein sinvolved on intracellular signaling pathways. Cisplatin and Doxorubicin are employed on chemotherapy, but…
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Keywords:
amine anti;
tris pyridylmethyl;
pyridylmethyl amine;
insights tris ... See more keywords
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Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt00104e
Abstract: Manganese(ii), copper(ii) and zinc(ii) complexes of four polydentate tripodal ligands (tachpyr (N,N',N''-tris(2-pyridylmethyl)-cis,cis-1,3,5-triaminocyclohexane), trenpyr (tris[2-(2-pyridylmethyl)aminoethyl]amine, tach3pyr (N,N',N''-tris(3-pyridylmethyl)-cis,cis-1,3,5-triaminocyclohexane) and tren3pyr (tris[2-(2-pyridylmethyl)aminoethyl]amine)) were characterized in both solution and solid states. A combined evaluation of potentiometric, UV-VIS, NMR and…
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Keywords:
copper;
metal;
tris pyridylmethyl;
tripodal ligands ... See more keywords
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Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt01425f
Abstract: Three new mononuclear Fe(ii) complexes have been prepared and characterized by the combination of tetradentate tris(2-pyridylmethyl)amine (TPMA) with three neutral bidentate ligands, such as ethylenediamine (en), 1,2-diaminopropane (pn) and 2-picolylamine (2-pic), in compounds [FeII(TPMA)(en)](ClO4)2 (1),…
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Keywords:
amine tpma;
neutral bidentate;
bidentate ligands;
tris pyridylmethyl ... See more keywords
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Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt03180k
Abstract: Flexible ligands that can adapt their donor strength have enabled unique reactivity in a wide range of inorganic complexes. Most examples are composed of flexible multi-dentate ligands containing a donor that can vary its interaction…
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Keywords:
strength;
adaptable ligand;
azaphosphatrane tpap;
tris pyridylmethyl ... See more keywords