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Published in 2019 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.201901155
Abstract: Two synthetic routes for the preparation of the water soluble 5,10,15‐tris(4‐sulfonatophenyl)corrole are reported. The first approach explores the chlorosulfonation reaction on the phosphorus complex of 5,10,15‐tris(4‐trimethylsilylphenyl)corrole. Following this route, the P complex of the target…
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Keywords:
chemistry;
sulfonatophenyl corrole;
corrole synthesis;
tris sulfonatophenyl ... See more keywords
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Published in 2018 at "Molecules"
DOI: 10.3390/molecules23123363
Abstract: A convenient protocol for the preparation of 5-phenyl-10,15,20-tris(4-sulfonatophenyl)porphyrin, a water-soluble porphyrin with unique aggregation properties, is described. The procedure relies on the one-pot reductive deamination of 5-(4-aminophenyl)-10,15,20-tris(4-sulfonatophenyl)porphyrin, that can be in turn easily obtained from…
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Keywords:
porphyrin synthesis;
sulfonatophenyl porphyrin;
phenyl tris;
porphyrin ... See more keywords