Articles with "trisubstituted indolines" as a keyword



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Enantioselective Synthesis of 2,2,3-Trisubstituted Indolines via Bimetallic Relay Catalysis of α-Diazoketones with Enones.

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Published in 2018 at "Organic letters"

DOI: 10.1021/acs.orglett.8b01744

Abstract: An efficient asymmetric intramolecular trapping of ammonium ylides of α-diazoketones with enones to synthesize indoline derivatives was realized. A Rh(II)/chiral N,N'-dioxide-Sc(III) complex bimetallic relay catalytic system was established. A series of optically active 2,2,3-trisubstituted indolines… read more here.

Keywords: trisubstituted indolines; synthesis trisubstituted; bimetallic relay; diazoketones enones ... See more keywords