Ruthenium Azobis(benzothiazole): Electronic Structure and Impact of Substituents on the Electrocatalytic Single-Site Water Oxidation Process.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03906
Abstract: The present article deals with the structurally and spectroelectrochemically characterized newer class of ruthenium-azoheteroarenes [RuII(Ph-trpy)(Cl)(L)]ClO4, [1]ClO4-[3]ClO4 (Ph-trpy: 4'-phenyl-2,2':6',2″-terpyridine; L1: 2,2'-azobis(benzothiazole) ([1]ClO4); L2: 2,2'-azobis(6-methylbenzothiazole) ([2]ClO4); L3: 2,2'-azobis(6-chlorobenzothiazole) ([3]ClO4)). A collective consideration of experimental (i.e., structural and… read more here.
Keywords: oxidation; trpy; clo4; water oxidation ... See more keywords