Phase-transfer Tsuji—Trost allylation of CH-acids with the assistance of palladium complexes with bidentate PIII—N—PIII ligands
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DOI: 10.1007/s11172-017-1788-6
Abstract: The Tsuji—Trost allylation of CH acids, in particular, those of the YCH2CO2Et type (Y = CO2Et, C(O)Me, CN), with allylic acetates in the K2CO3—DMF system in the presence of palladium catalysts with ligands RN(PPh2)2 (R… read more here.
Keywords: trost allylation; phase transfer; tsuji trost; allylation acids ... See more keywords
Stereoselective Synthesis of Fused Vinylcyclopropanes by Intramolecular Tsuji–Trost Cascade Cyclization
Sign Up to like & getrecommendations! Published in 2018 at "Organic Letters"
DOI: 10.1021/acs.orglett.8b02232
Abstract: A stereoselective intramolecular Tsuji–Trost cascade cyclization of (homo)allylic vicinal diacetates with a pendant β-ketoamide or related carbon nucleophile to give γ-lactam-fused vinylcyclopropanes is reported. In addition to two new rings, the products contain three new… read more here.
Keywords: cascade cyclization; fused vinylcyclopropanes; tsuji trost; trost cascade ... See more keywords
A novel intramolecular cyclization-induced fluorescent “turn-on” probe for detection of Pd2+ based on the Tsuji–Trost reaction
Sign Up to like & getrecommendations! Published in 2018 at "Analytical Methods"
DOI: 10.1039/c8ay00965a
Abstract: Palladium, as a toxic heavy metal, poses a great threat to the environment and human health. Therefore, it is essential to achieve the purpose of detecting trace amounts of palladium. In this paper, a probe… read more here.
Keywords: pd2; probe; based tsuji; trost reaction ... See more keywords