Tuning the Diradical Character of Pentacene Derivatives via Non-Benzenoid Coupling Motifs
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c02027
Abstract: The development of functional organic molecules requires structures of increasing size and complexity, which are typically obtained by the covalent coupling of smaller building blocks. Herein, with the aid of high-resolution scanning tunneling microscopy/spectroscopy and… read more here.
Keywords: tuning diradical; character; diradical character; character pentacene ... See more keywords
Fine-tuning the diradical character of molecular systems via the heteroatom effect.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/c9cc08538f
Abstract: Heteroatoms were introduced as a novel modification strategy for fine-tuning the diradical character of molecular systems. Both the diradical character and the singlet-triplet energy gaps of diketopyrrolopyrrole based phenoxyl diradicaloids decreased as the size of… read more here.
Keywords: fine tuning; molecular systems; tuning diradical; diradical character ... See more keywords