Copper complexes of 1,4-diazabutadiene ligands: Tuning of metal oxidation state and, application in catalytic C-C and C-N bond formation
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2019.119228
Abstract: Abstract Reaction of 1,4-diazabutadiene (p-RC6H4N = C(H)(H)C = NC6H4R-p; R = OCH3, CH3, H and Cl; abbreviated as L-R) with CuCl2·2H2O in methanol at ambient temperature (25 °C) affords a group of doubly chloro-bridged dicopper complexes of type [{CuI(L-R)Cl}2], designated as 1-R.… read more here.
Keywords: copper complexes; complexes diazabutadiene; copper; ligands tuning ... See more keywords
Tuning the metal insulator transition of vanadium dioxide on oxide nanosheets
Sign Up to like & getrecommendations! Published in 2021 at "Applied Physics Letters"
DOI: 10.1063/5.0059174
Abstract: For practical applications, tuning the metal-insulator transition (MIT) behavior of high-quality vanadium dioxide (VO2) on arbitrary substrates, such as Si and glass, is desirable. Here, we demonstrate the ability to tune the MIT temperature (TMIT)… read more here.
Keywords: insulator transition; vo2; vanadium dioxide; tuning metal ... See more keywords