Tuning the reactivity of cobalt-based H2 production electrocatalysts via the incorporation of the peripheral basic functionalities
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DOI: 10.1016/j.ccr.2020.213335
Abstract: Abstract The construction of an efficient, inexpensive, and durable H2 production electrocatalyst is considered as an indispensable tool for the inception of a hydrogen-mediated alternative energy technology. Recently, cobalt-based molecular complexes have emerged as one… read more here.
Keywords: cobalt based; tuning reactivity; production; cobalt ... See more keywords
Tuning the Reactivity of TEMPO during Electrocatalytic Alcohol Oxidations in Room-Temperature Ionic Liquids
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DOI: 10.1021/acssuschemeng.9b01823
Abstract: 2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO) is a promising, sustainable, metal-free mediator for oxidation of alcohols. In this contribution, we describe how the selectivity of TEMPO for electroca... read more here.
Keywords: tuning reactivity; reactivity tempo; tempo; electrocatalytic alcohol ... See more keywords
Tuning the reactivity of nitriles using Cu(ii) catalysis – potentially prebiotic activation of nucleotides† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc02513d
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DOI: 10.1039/c8sc02513d
Abstract: A synergistic system was established involving activating nucleotides with nitriles using Cu(ii) and protecting RNA degradation by byproducts of alpha-aminonitriles. read more here.
Keywords: potentially prebiotic; reactivity nitriles; using catalysis; tuning reactivity ... See more keywords
Tuning reactivity layer-by-layer: formic acid activation on Ag/Pd(111)†
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DOI: 10.1039/d0sc01461c
Abstract: The potential for tuning the electronic structure of materials to control reactivity and selectivity in heterogenous catalysis has driven interest in ultrathin metal films which may differ from their bulk form. Herein, a 1-atomic layer… read more here.
Keywords: layer; tuning reactivity; spectroscopy; formic acid ... See more keywords