Solvation Effects on Quantum Tunneling Reactions.
Sign Up to like & getrecommendations! Published in 2022 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.2c00151
Abstract: ConspectusA decisive factor for obtaining high yields and selectivities in organic synthesis is the choice of the proper solvent. Solvent selection is often guided by the intuitive understanding of transition state-solvent interactions. However, quantum-mechanical tunneling… read more here.
Keywords: solvation effects; quantum tunneling; hydrogen; solvent ... See more keywords
Ping-pong tunneling reactions, part 2: boron and carbon bell-clapper rearrangement
Sign Up to like & getrecommendations! Published in 2019 at "Pure and Applied Chemistry"
DOI: 10.1515/pac-2019-0401
Abstract: Abstract Anthracene can be used as a scaffold for intramolecular SN2 degenerate reactions of the “bell clapper” type, where a central boron atom or its isoelectronic carbocation bonds alternatively towards one or the other lateral… read more here.
Keywords: reactions part; pong tunneling; ping pong; tunneling reactions ... See more keywords