Unusual Mn5 cluster with a ‘twisted bow-tie’ topology and MnIIMnIII2MnIV2 oxidation states: Synthesis, structure, and magnetic properties
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DOI: 10.1016/j.poly.2021.115141
Abstract: Abstract The ‘reductive aggregation’ procedure involving the reaction of MnO4- in MeOH in the presence of a carboxylic acid has been extended for the first time to the use of a dicarboxylic acid and the… read more here.
Keywords: bpy; tie topology; topology; oxidation states ... See more keywords
Ligand-directed synthesis of {Mn} twisted bow-ties.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt02430d
Abstract: Two isostructural polymetallic complexes [Mn(μ3-O)2(CH3COO)4(L1)4]- and [Mn(μ3-O)2(CH3COO)4(L2)4]- have been synthesised by using two Schiff base ligands derived from 3,5-diamino-1,2,4-triazole, following two different preparative routes, either using the pre-formed ligand (for L1) or via a metal-mediated… read more here.
Keywords: twisted bow; synthesis twisted; ligand directed; synthesis ... See more keywords