Phosphorescent monometallic and bimetallic two-coordinate Au(I) complexes with N-heterocyclic carbene and aryl ligands
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.120188
Abstract: Abstract A series of mononuclear and binuclear two coordinate Au(I) complexes consisting of a MAC carbene ligand (1,3-bis(2,6-diisopropylphenyl)-5,5-dimethyl-4-keto-tetrahydropyridylidene) and an aryl ligand, including phenyl, biphenyl, naphthyl and anthryl, are reported. The oxidation potential is controlled… read more here.
Keywords: ligand; coordinate complexes; two coordinate; carbene ... See more keywords
Rational Design to Activate Tetrafluoromethane by Two-Coordinate Borinium.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03900
Abstract: The activation of tetrafluoromethane (CF4) is quite challenging. The current methods have a high decomposition rate but are expensive, and therefore, their widespread use is limited. Here, inspired by the successful C-F activation within saturated… read more here.
Keywords: two coordinate; design activate; tetrafluoromethane; coordinate borinium ... See more keywords
Two-Coordinate, Late First-Row Transition Metal Amido Derivatives of the Bulky Ligand -N(SiPr i3)Dipp (Dipp = 2,6-diisopropylphenyl): Effects of the Ligand on the Stability of Two-Coordinate Copper(II) Complexes.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b01159
Abstract: The synthesis and spectroscopic, structural, and magnetic characterization of the quasi-linear metal(II) bis(amides) M{N(SiPr i3)Dipp}2 [Dipp = C6H3-2,6-Pr i3; M = Fe (1), Co (2), or Zn (3)] are described. The magnetic data demonstrate the… read more here.
Keywords: two coordinate; copper; metal; dipp ... See more keywords
A Two-Coordinate Neutral Germylene Supported by a β-Diketiminate Ligand in the Radical State
Sign Up to like & getrecommendations! Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00400
Abstract: Using the new β-diketimine 1a (PhCH(PhC═N-Dip)2, Dip = 2,6-iPr2C6H3), which possesses three phenyl groups at the ligand backbone, we synthesized the β-diketiminato germylene chloride 2 (LGeCl, L = [PhC(PhCN-Dip)2]−). The β-diketiminato germanium radical complex 3… read more here.
Keywords: neutral germylene; coordinate neutral; two coordinate; dip ... See more keywords
Reactivity of a Two-Coordinate Cobalt(0) Cyclic (Alkyl)(amino)carbene Complex
Sign Up to like & getrecommendations! Published in 2020 at "Organometallics"
DOI: 10.1021/acs.organomet.9b00875
Abstract: Cyclic (alkyl)(amino)carbenes (cAACs) are the merely known ligand set being capable of stabilizing two-coordinate cobalt(0) complexes. While two complexes of the type [(R2-cAAC)2Co] [R2-cAAC = 5,5-... read more here.
Keywords: coordinate cobalt; two coordinate; reactivity two; alkyl amino ... See more keywords
Bimetallic Mechanism for Alkyne Cyclotrimerization with a Two-Coordinate Fe Precatalyst
Sign Up to like & getrecommendations! Published in 2020 at "ACS Catalysis"
DOI: 10.1021/acscatal.0c01828
Abstract: The two-coordinate compound (IPr)Fe[N(SiMe3)DIPP] (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene; DIPP = 2,6-diisopropylphenyl) catalyzes the cyclotrimerization of alkynes to arenes. Tre... read more here.
Keywords: bimetallic mechanism; coordinate; two coordinate; mechanism alkyne ... See more keywords
π-Extended Ligands in Two-Coordinate Coinage Metal Complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c06948
Abstract: Two-coordinate carbene-MI-amide (cMa, MI = Cu, Ag, Au) complexes have emerged as highly efficient luminescent materials for use in a variety of photonic applications due to their extremely fast radiative rates through thermally activated delayed… read more here.
Keywords: coordinate coinage; two coordinate; ligands two; extended ligands ... See more keywords
Cyclobutenylidene: A Multifaceted Two-Coordinate Carbon Species Obtained via Skeletal Editing of a Cyclopropenylidene.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c01906
Abstract: C4H4 isomers not only serve as a basis to understand the chemical properties of hydrocarbons but are possible intermediates in combustion and organic reactions in outer space. Cyclobutenylidene (CBY), an elusive C4H4 isomer, is often… read more here.
Keywords: multifaceted two; carbon; two coordinate; carbon species ... See more keywords
A Series of Two-Coordinate Group-15 Element (P, As, Sb, Bi) Centered Radicals Having Bulky Alkyl Groups
Sign Up to like & getrecommendations! Published in 2018 at "Bulletin of the Chemical Society of Japan"
DOI: 10.1246/bcsj.20180057
Abstract: Two-coordinate group-15 element centered radicals that bear a lone pair and an unpaired electron on the same group-15 atoms have received much attention in group-15 element chemistry. We previously synthesized an isolable dialkylphosphinyl radical, 2,2,5,5-tetrakis(trimethylsilyl)-1-phosphacyclopentane-1-yl… read more here.
Keywords: group element; coordinate group; two coordinate; group ... See more keywords