Surface‐Interface Engineering of Electrocatalysts for Two‐Electron Water Oxidation Reaction to Produce H2O2
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202413243
Abstract: Electrochemical two‐electron water oxidation reaction (2e− WOR) driven by renewable energy offers an attractive route to produce H2O2, while the corresponding electrocatalyst still requires further improvement for the activity, selectivity, and the resulting H2O2 yield.… read more here.
Keywords: surface interface; two electron; surface; interface engineering ... See more keywords
Field‐Regulated Dynamics at Electrode/Electrolyte Interface Toward Efficient H2O2 Generation via Two‐Electron Water Oxidation
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202513578
Abstract: Two‐electron water oxidation reaction (2e− WOR) holds significant promise for efficient H2O2 synthesis, but the activity of previous studies is not satisfactory. Most studies have focused on thermodynamic aspects, but neglected the critical role of… read more here.
Keywords: efficient h2o2; h2o2 generation; field; two electron ... See more keywords
A Tiron Redox Mediator Enabling Dominant Two‐Electron Transfer Energy Storage in MnO 2 Cathode Materials for Aqueous Zn Batteries
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202519798
Abstract: Rechargeable aqueous Zn‐MnO 2 batteries are promising for large‐scale energy storage. A two‐electron transfer reaction of MnO 2 /Mn 2+ is available for the cathode, delivering a high theoretical capacity of 616 mAh g −1… read more here.
Keywords: energy storage; electron transfer; cathode; two electron ... See more keywords
Electrochemical Oxygen Reduction to Hydrogen Peroxide via a Two‐Electron Transfer Pathway on Carbon‐Based Single‐Atom Catalysts
Sign Up to like & getrecommendations! Published in 2020 at "Advanced Materials Interfaces"
DOI: 10.1002/admi.202001360
Abstract: Electrochemical reduction of oxygen is considered as a new strategy to achieve decentralized preparation of hydrogen peroxide (H2O2) in a green manner. As a promising new type of catalytic material, carbon‐based single‐atom catalysts can achieve… read more here.
Keywords: two electron; carbon based; based single; atom catalysts ... See more keywords
Coordination of 3‐Methylindole‐Based Tripodal Tetraphosphine Ligands to Iron(+II), Cobalt(+II), and Nickel(+II) and Investigations of their Subsequent Two‐Electron Reduction
Sign Up to like & getrecommendations! Published in 2018 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201701209
Abstract: We report the coordination chemistry of indole based tripodal tetraphosphine ligands to iron(II), cobalt(II) and nickel(II). These complexes are formed by simple synthetic protocols and were characterized by a combination of spectroscopic techniques and single‐crystal… read more here.
Keywords: coordination; two electron; chemistry; geometry ... See more keywords
A full‐pivoting algorithm for the Cholesky decomposition of two‐electron repulsion and spin‐orbit coupling integrals
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Computational Chemistry"
DOI: 10.1002/jcc.25062
Abstract: A significant reduction in the computational effort for the evaluation of the electronic repulsion integrals (ERI) in ab initio quantum chemistry calculations is obtained by using Cholesky decomposition (CD), a numerical procedure that can remove… read more here.
Keywords: chemistry; two electron; orbit coupling; cholesky decomposition ... See more keywords
Synergetic Dual-Ion Centers Boosting Metal Organic Framework Alloy Catalysts toward Efficient Two Electron Oxygen Reduction.
Sign Up to like & getrecommendations! Published in 2022 at "Small"
DOI: 10.1002/smll.202202248
Abstract: Herein, a strategy of synergetic dual-metal-ion centers to boost transition-metal-based metal organic framework (MOF) alloy nanomaterials as active oxygen reduction reaction (ORR) electrocatalysts for efficient hydrogen peroxide (H2 O2 ) generation is proposed. Through a… read more here.
Keywords: ion centers; synergetic dual; metal organic; two electron ... See more keywords
Natural orbitals of the ground state of the two-electron harmonium atom
Sign Up to like & getrecommendations! Published in 2018 at "Theoretical Chemistry Accounts"
DOI: 10.1007/s00214-018-2362-5
Abstract: AbstractThe radial components of the natural orbitals (NOs) pertaining to the $$^1S_+$$1S+ ground state of the two-electron harmonium atom are found to satisfy homogeneous differential equations at the values of the confinement strength $$\omega $$ω… read more here.
Keywords: natural orbitals; ground state; electron harmonium; two electron ... See more keywords
Collinear configuration of the helium atom and two-electron ions
Sign Up to like & getrecommendations! Published in 2020 at "Annals of Physics"
DOI: 10.1016/j.aop.2020.168306
Abstract: Abstract Collinear configurations of the helium-like atomic systems, relevant, e.g., for the quasifree mechanism of the double photoionization of helium, are studied, parameterized by the single scalar parameter − 1 ≤ λ ≤ 1 (“collinear… read more here.
Keywords: helium; collinear configurations; configurations derived; configuration ... See more keywords
Designer Two-Electron Storage Viologen Anolyte Materials for Neutral Aqueous Organic Redox Flow Batteries
Sign Up to like & getrecommendations! Published in 2017 at "Chem"
DOI: 10.1016/j.chempr.2017.11.001
Abstract: Summary Aqueous organic redox flow batteries (AORFBs) are highly attractive for large-scale energy storage because redox-active organic molecules are synthetically tunable, sustainable, and potentially low cost. Here, we show that rational molecular engineering yielded a… read more here.
Keywords: storage; flow batteries; two electron; redox ... See more keywords
An unsymmetrical two-electron viologens anolyte for salt cavern redox flow battery
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Power Sources"
DOI: 10.1016/j.jpowsour.2021.229659
Abstract: Abstract Salt cavern with a volume of hundreds of thousands of cubic meters for storing electrolyte has been considered as a promising large-scale storage technology. However, the solubility and electrochemical stability of active organic species… read more here.
Keywords: salt cavern; unsymmetrical two; two electron; electron viologens ... See more keywords