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Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c00012
Abstract: We describe the first catalytic generation of Fischer-type acyloxy Rh(II)-carbenes from carboxylic acids and Rh(II)-carbynoids. This novel class of transient donor/acceptor Rh(II)-carbenes evolved through a cyclopropanation process providing access to densely functionalized cyclopropyl-fused lactones with…
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Keywords:
carbenes carbynoids;
type carbenes;
generating fischer;
fischer type ... See more keywords