An Efficient Synthetic Approach to trans‐(NHC)2Pd(R)Br Type Complexes and Their Use in Suzuki–Miyaura Cross‐Coupling Reactions
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700017
Abstract: Mixed organo-halo palladium complexes of the type trans-(NHC)2Pd(R)Br were conveniently obtained from trans-(NHC)2PdBr2 type complexes by the ligand substitution reaction. In particular, the trans-[1-(1S)-menthyl-4-(R1)-1,2,4-triazol-5- ylidene]2Pd(R2)Br [R1 = Et, R2 = CH2Ph (3a1); R1 = Et,… read more here.
Keywords: type complexes; nhc 2pd; trans nhc; cross ... See more keywords
Synthesis of New Pd(NHC)-PEPPSI Type Complexes as Catalysts toward C-C Cross-Coupling Reactions
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2021.130883
Abstract: Abstract The goal of our research is to synthesis homogeneous catalysts, for which we take start from two novel precursors of 1-(3-methyloxetane-3-yl)benzimidazole and 5,6-dimethyl-1-((3-methyloxetane-3-yl)benzimidazole. A series of ligands containing 1,3-disubstituted benzimidazolium salts were synthesized from… read more here.
Keywords: nhc peppsi; type complexes; catalysts toward; peppsi type ... See more keywords
Stereoselective formation and spectroscopic studies of [Cr(edda or eddp)(N N)]-type complexes (edda = ethylenediamine-N,N′-diacetate; eddp = ethylenediamine-N,N′-dipropionate)
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2018.12.040
Abstract: Abstract [Cr(edda or eddp)(N N)]-type complexes (edda = ethylenediamine-N,N′-diacetate, eddp = ethylenediamine-N,N′-dipropionate; N N = 1,2-ethanediamine (en), 2,2′-bipyridine (bpy) and 1,10-phenanthroline (phen)) were formed with stereoselectivity. These complexes were characterized by UV–Vis and IR absorption spectra and X-ray crystal analysis. The… read more here.
Keywords: type complexes; ligand; eddp type; edda ... See more keywords
Update of the concept of type 5 resistant starch (RS5): Self-assembled starch V-type complexes
Sign Up to like & getrecommendations! Published in 2021 at "Trends in Food Science and Technology"
DOI: 10.1016/j.tifs.2021.01.078
Abstract: Abstract Background All starch fractions not digested and absorbed in the small intestine of healthy humans are considered resistant starch (RS), and their habitual intake has been associated with different beneficial effects on health. In… read more here.
Keywords: starch type; resistant starch; type complexes; starch ... See more keywords
Exploring the Coordination Chemistry of N2 with Technetium PNP Pincer-Type Complexes.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00503
Abstract: Dinitrogen (N2) complexes of technetium (99Tc) are rare, and only two examples have been reported. To complement this important class of complexes also for 99Tc, two different pincer-type complexes of 99Tc were studied to assess… read more here.
Keywords: pincer; dinitrogen; type complexes; pincer type ... See more keywords
A New Family of Fe4Ln4 (Ln = DyIII, GdIII, YIII) Wheel type Complexes with Ferromagnetic Interaction, Magnetocaloric Effect and Zero-field SMM Behavior
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic Chemistry Frontiers"
DOI: 10.1039/d1qi00781e
Abstract: In this work, we report three isostructural Fe4Ln4 wheel type complexes with molecular formula [{Fe4(dea)4Dy4(deaH)8(µ2-OMe)4}(NO3)4]·4(H2O) (1), [{Fe4(dea)4Gd4(deaH)8(µ2-OMe)4}‧(NO3)4]·4(H2O)·4(MeOH) (2) and [{Fe4(dea)4Y4(deaH)8(µ2-OMe)4}(NO3)4]·4(H2O)·6(MeOH) (3), (where dea = diethanolamine). Detailed structural analysis disclose that... read more here.
Keywords: wheel type; fe4ln4; type complexes; dea ... See more keywords
PtII(C^N)(N-donor ligand)Cl-type complexes showing highly sensitive aggregation-induced phosphorescent emission (AIPE) behavior fulfilled by long-size ligands and distorted molecular configuration
Sign Up to like & getrecommendations! Published in 2023 at "Dalton Transactions"
DOI: 10.1039/d3dt00238a
Abstract: A series of four-coordinated PtII(C^N)(N-donor ligand)Cl-type complexes have been synthesized through combination between long-size C^N-type and N-donor ligands. In addition, by variating the coordinating site in the N-donor ligand, distorted... read more here.
Keywords: type complexes; ptii donor; ligand; donor ligand ... See more keywords
Analysis two types of K complexes on the human EEG based on classical continuous wavelet transform.
Sign Up to like & getrecommendations! Published in 2023 at "Chaos"
DOI: 10.1063/5.0143284
Abstract: In our work, we compare EEG time-frequency features for two types of K-complexes detected in volunteers performing the monotonous psychomotor test with their eyes closed. Type I K-complexes preceded spontaneous awakenings, while after type II… read more here.
Keywords: type complexes; two types; types complexes; type ... See more keywords
Tetrel-Bond Interactions Involving Metallylenes TH2 (T = Si, Ge, Sn, Pb): Dual Binding Behavior
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28062577
Abstract: The dual binding behavior of the metallylenes TH2 (T = Si, Ge, Sn, Pb) with some selected Lewis acids (T’H3F, T’ = Si, Ge, Sn, Pb) and bases (N2, HCN, CO, and C6H6) has been… read more here.
Keywords: type complexes; metallylenes th2; type; binding behavior ... See more keywords