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Published in 2022 at "ACS Catalysis"
DOI: 10.1021/acscatal.2c00485
Abstract: In this contribution, we report chemoenzymatic bromodecarboxylation (Hunsdiecker-type) of α,ß-unsaturated carboxylic acids. The extraordinarily robust chloroperoxidase from Curvularia inaequalis (CiVCPO) generated hypobromite from H2O2 and bromide, which then spontaneously reacted with a broad range of…
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Keywords:
type decarboxylative;
hunsdiecker;
decarboxylative bromination;
chemoenzymatic hunsdiecker ... See more keywords