Saturated Heavier Group 14 Compounds as σ -Electron-Acceptor (Z-Type) Ligands.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical record"
DOI: 10.1002/tcr.201600061
Abstract: This review article describes the chemistry of transition-metal complexes containing heavier group 14 elements (Si, Ge, and Sn) as the σ-electron-acceptor (Z-type) ligands and discusses the characteristics of bonds between the transition metal and Z-type… read more here.
Keywords: electron acceptor; type; type ligands; acceptor type ... See more keywords
Biological activities of polypyridyl-type ligands: implications for bioinorganic chemistry and light-activated metal complexes.
Sign Up to like & getrecommendations! Published in 2021 at "Current opinion in chemical biology"
DOI: 10.1016/j.cbpa.2021.01.016
Abstract: Polypyridyl coordinating ligands are common in metal complexes used in medicinal inorganic chemistry. These ligands possess intrinsic cytotoxicity, but detailed data on this phenomenon are sparse, and cytotoxicity values vary widely and are often irreproducible.… read more here.
Keywords: biological activities; chemistry; metal; metal complexes ... See more keywords
Effect of Buchwald-type ligands on platinum catalyzed hydrosilylation of vinyl terminated polydimethylsiloxane
Sign Up to like & getrecommendations! Published in 2019 at "Mendeleev Communications"
DOI: 10.1016/j.mencom.2019.07.035
Abstract: The effect of Buchwald-type ligands on the platinum catalyzed hydrosilylation of vinyl-terminated polydimethylsiloxane has been studied by differential scanning calorimetry of platinum catalyst-containing silicone compositions. Dialkyl(biphenyl-2-yl)phosphines bearing bulky substituents at phosphorus atom are efficient inhibitors… read more here.
Keywords: buchwald type; hydrosilylation; type ligands; ligands platinum ... See more keywords
An unprecedented formation of new copper(II) complexes as bioactive materials based on copper-catalyzed click reaction
Sign Up to like & getrecommendations! Published in 2021 at "Polyhedron"
DOI: 10.1016/j.poly.2021.115084
Abstract: Abstract 1,2-cyclohexanedione-bis(p-fluorobenzohydrazone) (L) was synthesized as a bisaroylhydrazone type compound. This molecule was reacted with Cu(NO3)2·3H2O in CH3CN under ambient conditions, and consequently, different types of complexes were obtained: mononuclear copper(II) complexes with the general… read more here.
Keywords: type ligands; copper; copper complexes; binding nitrate ... See more keywords
Mono- and polynuclear Ag(i) complexes of N-functionalized bis(diphenylphosphino)amine DPPA-type ligands: synthesis, solid-state structures and reactivity.
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DOI: 10.1039/c6dt04755f
Abstract: The reactivity of the N-functionalized DPPA-type ligands (Ph2P)2N(p-Z)C6H4 [Z = H (1a), SMe (1b), OMe (1c)] with AgBF4 was investigated and revealed an unexpected influence of the para substituent Z of the N-aryl ligand. In… read more here.
Keywords: solid state; dppa type; bf4; bf4 bf4 ... See more keywords
An Efficient and Modular Route to C3*-TunePhos-Type Ligands
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DOI: 10.1055/s-0036-1588421
Abstract: An efficient and modular synthetic route to the bidentate C3*-TunePhos was developed, which allowed tunable steric and electronic effects of the ligands. This novel chemical technology highlights a versatile C3*-dibromodiphenyl intermediate that was accomplished by… read more here.
Keywords: efficient modular; type ligands; type; tunephos ... See more keywords