A Chemically Stable Hofmann-Type Metal-Organic Framework with Sandwich-Like Binding Sites for Benchmark Acetylene Capture.
Sign Up to like & getrecommendations! Published in 2020 at "Advanced materials"
DOI: 10.1002/adma.201908275
Abstract: The realization of porous materials for highly selective separation of acetylene (C2 H2 ) from various other gases (e.g., carbon dioxide and ethylene) by adsorption is of prime importance but challenging in the petrochemical industry.… read more here.
Keywords: hofmann type; chemically stable; type; stable hofmann ... See more keywords
Mercury removal from flue gas using UiO-66-type metal-organic frameworks grafted with organic functionalities
Sign Up to like & getrecommendations! Published in 2021 at "Fuel"
DOI: 10.1016/j.fuel.2020.119807
Abstract: Abstract UiO-66-type metal-organic frameworks (MOF) grafted with organic functionalities (–Br, –NO2 and –NH2) are introduced to investigate the elemental mercury (Hg0) removal from flue gas, and the effect for adding linkers on Hg0 removal is… read more here.
Keywords: removal; metal organic; hg0; uio type ... See more keywords
UiO-type metal-organic frameworks with NHC or metal-NHC functionalities for N-methylation using CO2 as the carbon source.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc06659d
Abstract: We demonstrate the first metal-organic framework (MOF) that catalyzes N-methylation of amines using 1 atm CO2 and phenylsilane under ambient conditions. Compared with its homogeneous analog, the incorporation of N-heterocyclic carbene (NHC) into the MOF… read more here.
Keywords: methylation; metal organic; metal; uio type ... See more keywords