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Published in 2020 at "Catalysis Letters"
DOI: 10.1007/s10562-020-03432-4
Abstract: A new amphipathic lindqvist-type polyoxometalate-based TiO2 nanofibres catalysts (50-DTA-MoO-TiO2NF, DTA = CH3(CH2)11(CH3)3N, MoO = Mo6O192-, TiO2 NF = TiO2 nanofibres, the weight percentage of DTA-MoO was 50%) was obtained by electrospinning and applied in desulfurization…
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Keywords:
desulfurization;
polyoxometalate based;
type polyoxometalate;
amphipathic lindqvist ... See more keywords
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Published in 2019 at "Research on Chemical Intermediates"
DOI: 10.1007/s11164-019-03789-1
Abstract: The manufacture of single-atom transition metal-doping carbon nanocomposites as electrode materials is crucial for electrochemical energy storage with high energy and power density. However, the simple strategy for preparation of such active materials with controlled…
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Keywords:
type polyoxometalate;
anderson type;
energy;
pom rgo ... See more keywords
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Published in 2021 at "Catalysis Communications"
DOI: 10.1016/j.catcom.2020.106256
Abstract: Abstract Anderson-type polyoxometalate (POM) catalysts were synthesized and applied for deep oxidative desulfurization of model fuel containing dibenzothiophene. O2 contained in air was used as oxidant under mild conditions. The influence of the nature of…
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Keywords:
desulfurization;
type polyoxometalate;
anderson type;
model fuel ... See more keywords
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Published in 2017 at "Polyhedron"
DOI: 10.1016/j.poly.2016.12.040
Abstract: Abstract Five new Anderson-type polyoxometalate-based metal–organic complexes, [Cu4(μ3-OH)2(H2O)6(4-dpye)2(TeMo6O24)]·2H2O (1), [Cu(4-dpyb)(CrMo6(OH)6O18)2(H2O)2][Cu(4-dpyb)(H2O)4](4-H2dpyb)·6H2O (2), H[Cu2(3-dpyb)2(C2O4)(CrMo6(OH)6O18)]·8H2O (3), [Cu2(4-dpyh)(CrMo6(OH)5O19)(H2O)8]·10H2O (4) and [Cu4(μ2-OH)(μ3-OH)(H2O)6(4-dpyh)(TeMo6O24)]·H2O (5) (4-dpye = N,N′-bis(4-pyridinecarboxamide)-1,2-ethane, 4-dpyb = N,N′-bis(4-pyridinecarboxamide)-1,4-butane, 3-dpyb = N,N′-bis(3-pyridinecarboxamide)-1,4-butane, 4-dpyh = N,N′-bis(4-pyridinecarboxamide)-1,6-hexane), were hydrothermally prepared and structurally characterized by single crystal X-ray diffraction analyses and…
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Keywords:
type polyoxometalate;
anderson type;
h2o;
dpyb ... See more keywords
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Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.04.058
Abstract: Abstract Developing new low-cost and efficient proton-conducting materials remains an attractive and challenging task. Herein, a Preyssler-type polyoxometalate derived coordination compound had been synthesized with a hydrothermal method, namely, H4.5NaCo5(2-MI)15.5(2-MI)3 [NaP5W30O110]·5H2O (1) (where 2-methylimidazole is…
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Keywords:
type polyoxometalate;
preyssler type;
polyoxometalate;
proton conducting ... See more keywords
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Published in 2019 at "Communications Chemistry"
DOI: 10.1038/s42004-019-0111-x
Abstract: Polyoxometalate based solids are promising candidates of proton-conducting solid electrolytes. In this work, a Preyssler-type polyoxometalate is crystallized with potassium ions and poly(allylamine), which is also a good proton conductor, from aqueous solutions. Here we…
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Keywords:
polyoxometalate;
type polyoxometalate;
poly allylamine;
proton ... See more keywords
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Published in 2021 at "CrystEngComm"
DOI: 10.1039/d1ce00059d
Abstract: Four Preyssler-type polyoxometalate-based organic–inorganic hybrid materials were synthesized as non-enzymatic H2O2 electrochemical sensors, with high sensitivity and low detection limit.
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Keywords:
type polyoxometalate;
polyoxometalate based;
preyssler type;
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Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt00499a
Abstract: Bi3+ and Pb2+ uptake by a monolacunary Keggin-type [PW11O39]7- anion leads to the formation of [PW11O39Bi]4- and [PW11O39Pb]5- complexes with a stereochemically active lone pair at the incorporated heterometal. The two complexes were isolated as…
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Keywords:
type polyoxometalate;
keggin type;
experimental theoretical;
iii experimental ... See more keywords
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Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc05904e
Abstract: A novel supramolecular complex Li3Cl[(HPW12O40)(H24C12O6)3(CH3CN)2] {CR-PW12} was confirmed first to apply as a sulfur host in lithium-sulfur batteries. The {CR-PW12}@S cathode exhibits a reversible capacity of 1120 mA h g-1 at 1.0 C and excellent…
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Keywords:
keggin type;
lithium sulfur;
sulfur;
type polyoxometalate ... See more keywords