Modification of the pore environment in UiO-type metal-organic framework toward boosting the separation of propane/propylene
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2020.126428
Abstract: Abstract The separation of propane (C3H8) from propylene (C3H6) to obtain high purity C3H6 as a petrochemical raw material is an important, but challenging process. In the traditional industrial process, the separation mainly relies on… read more here.
Keywords: uio type; process; separation; separation propane ... See more keywords
Mercury removal from flue gas using UiO-66-type metal-organic frameworks grafted with organic functionalities
Sign Up to like & getrecommendations! Published in 2021 at "Fuel"
DOI: 10.1016/j.fuel.2020.119807
Abstract: Abstract UiO-66-type metal-organic frameworks (MOF) grafted with organic functionalities (–Br, –NO2 and –NH2) are introduced to investigate the elemental mercury (Hg0) removal from flue gas, and the effect for adding linkers on Hg0 removal is… read more here.
Keywords: removal; metal organic; hg0; uio type ... See more keywords
Single-Crystalline UiO-67-Type Porous Network Stable to Boiling Water, Solvent Loss, and Oxidation.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b00404
Abstract: With methylthio groups flanking the carboxyl groups, the 3,3',5,5'-tetrakis(methylthio)biphenyl dicarboxylate (TMBPD) linker forms a zirconium(IV) carboxylate porous framework featuring the topology of the UiO-67 prototype, i.e., with a face-centered-cubic array of the Zr6O4(OH)4 clusters. Thioether… read more here.
Keywords: oxidation; water; uio type; single crystalline ... See more keywords
Linker Engineering toward Full-Color Emission of UiO-68 Type Metal-Organic Frameworks.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c04810
Abstract: Luminescent metal-organic frameworks (LMOFs) demonstrate strong potential for a broad range of applications due to their tunable compositions and structures. However, the methodical control of the LMOF emission properties remains a great challenge. Herein, we… read more here.
Keywords: uio type; organic frameworks; metal organic; emission ... See more keywords
UiO-type metal-organic frameworks with NHC or metal-NHC functionalities for N-methylation using CO2 as the carbon source.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc06659d
Abstract: We demonstrate the first metal-organic framework (MOF) that catalyzes N-methylation of amines using 1 atm CO2 and phenylsilane under ambient conditions. Compared with its homogeneous analog, the incorporation of N-heterocyclic carbene (NHC) into the MOF… read more here.
Keywords: methylation; metal organic; metal; uio type ... See more keywords
Solid-phase rapid synthesis of hierarchical UiO-type metal-organic frameworks as excellent solid acid catalysts for acetalization of benzaldehyde with alcohol.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt00915g
Abstract: Functionalized metal-organic frameworks (MOFs) have been used in a wide range of applications. Although the development of functionalized MOFs with plentiful open metal sites (defects) provides an avenue for targeted reactions, creating such defects remains… read more here.
Keywords: organic frameworks; metal organic; solid phase; metal ... See more keywords