Resolving Ultrafast Photoinitiated Dynamics of the Hachimoji 5‐aza‐7‐deazaguanine Nucleobase: Impact of Synthetically Expanding the Genetic Alphabet †
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DOI: 10.1111/php.13688
Abstract: The guanine derivative, 5‐aza‐7‐deazaguanine (5N7CG) has recently been proposed as one of four unnatural bases, termed Hachimoji (8‐letter) to expand the genetic code. We apply steady‐state and time‐resolved spectroscopy to investigate its electronic relaxation mechanism… read more here.
Keywords: photoinitiated dynamics; dynamics hachimoji; state; ultrafast photoinitiated ... See more keywords